(1)sin²2B+sin2BsinB+cos2B=1 ∴4(sinB)^2*(cosB)^2+2(sinB)^2*cosB-2(sinB)^2=0,sinB>0,∴2(cosB)^2+cosB-1=0,cosB=-1(舍),cosB=1/2,∴∠B=60°。(2)A+C=120°,a+c=3(sinA+sinC)/sin60°=4(√3)sin[(A+C)/2]cos[(A-C)/2]=6cos[(A-C)/2],其最大值是6.